(EC+β+) Decay of 130Pm and 128Pr

¹³⁰Pm and ¹²⁸ Pr were produced by irradiation of ⁹⁶Ru with 171MeV ³⁶Ar beam,and a He-jet recoil tape transport system transported radioactivities to shielded reigon. Based on X-γ-t and γ-γ-t coincidence measurements ,the (EC+β⁺)decay scheme of ¹³⁰Pm was proposed for the first time and the (EC+β⁺)decay scheme of ¹²⁸Pr was revised.     

Determination of Catecholamine Concentration by Reverse-Phase Liquid Chromatography with Elecrtrochemical Detector in Plasma

The plasma catecholamine include mainly norepinephrine(NE),epinephrine(E) and dopamine (DA). The catecholamines(CA) are nervous mediator which are synthesized and release from sympathetic system. It is significant for diagnosing disease and researching surgical stress in clinic that determine the concentration of catecholamine in plasma.The analytic method had traditionally radioactive enzyme, fluorescent spectrometry and high performance liquid chromatography(HPLC). This paper describe an analytical technique that determine the concentration of NE, E and DA in plasma using HPLC-ED. The method is sensitive, fast and accuracy,and can be applied for the clinical diagnosis and laboratory research.     

Spectroelectrochemical Study on Radical Intermediate of Coenzyme Q10 at Silver Electrode

The radical intermediate (ubisemiquinone) of CoenzymeQ₁₀ (CoQ₁₀) had been observed in nonpolar solvents by spectroscopic techniques.1 The present work investigates the radical speices, as well known, it is extremely unstable in polar solvents, in ethanol/water system through spectroelectrochemical techniques including in situ UV/Vis,EPR and NMR.     

双氯乙酸苯二酚酯的合成

以丙酮为溶剂、三乙胺为缚酸剂,苯二酚10mmol,n(苯二酚)：n(氯乙酰氯)=1.0：3．0,在0℃～5℃的冰水浴下反应30min后再加热回流4h～5h,合成了两个双氯乙酸苯二酚酯(收率分别为63．4％,70．2％),其结构经元素分析、1H NMR和MS确认。     

非金属二元氢化物分子振动固有频率与pKa常数的定量关系

提出了非金属二元氢化物分子振动固有频率的计算原理与方法.将基频和总频作为结构信息指数用于非金属二元氢化物的分子结构与pK_a常数的定量关系研究,结果表明,其相关系数大于0.995,得到的回归方程用于pK_a的计算,计算值与实验值比较,平均绝对误差小于1.82.     

First-Order-Like Transition in Inhomogeneously Broadened Two-Mode Ring Laser Gain-Noise Model

An inhomogeneously broadened two-mode ring laser gain-noise model taking account of both full saturation effects and multiplicative noise induced by gain fluctuations is investigated. By using a corresponding Fokker-Planck equation and perturbation theory proposed by Graham et al. the joint stationary distribution for light intensities is obtained. It is found that a first-order-like transition occurs when laser is operated off resonance.     

在(TPA)2O-Na2O-SiO2-H2O体系中MFI型硅沸石的结晶行为(Ⅱ)──硅沸石微细晶粒的低温合成及其结构和性质表征

以白炭黑和硅溶胶为桂源, 在(TPA)₂O-Na₂O-SiO₂－H₂O体系60℃下合成了高结晶度纯相硅佛石.由SEM测得其晶粒尺寸为0.2μm和0.45μm, 用XRD线宽法测得的为0.02μm.与180℃时合成的硅沸石样品相比, 低温合成的细晶粒硅沸石已具备纳米级材料的若干特性.其正乙烷吸附量反常增大;XRD、FTIR、²⁹SiMASNMR和TG／DTG／DTA的研究证明, 其结构破坏温度和单斜／正交对称性相转变温度明显下降, 桂羟基缺陷明显增加.     

氟改性聚氨酯乳液的合成及其表面性能

氟改性聚氨酯乳液的合成及其表面性能;氟改性;聚氨酯乳液;表面性能     

基于带隙分析的三维反蛋白石光子晶体的非理想态结构参数的求解

应用平面波展开法分析了三维反蛋白石结构光子晶体的带隙性质;计算了沿[111]方向入射时其赝带隙(第一、第三赝带)中心频率分别与填隙材料在模板中填充率ff、模板煅烧因子sf的关系曲线:随ff的减小,v增大;随sf的增大,v随之增大,非理想状态下,ff＜100;、sf＞1,因此较理想态发生蓝移;由此提出了求解平均填充率ffev与平均煅烧因子sfev的计算框图.     

广义Drinfeld-Sokolov方程的行波解的分支

用Ansatz方法和动力系统理论研究了广义Drinfeld-Sokolov方程的行波解．在给定的两组参数条件下,得到了广义Drinfeld-Sokolov方程更多的孤立波解,扭子和反扭子波解及周期波解,并给出这些行波解精确的参数表示．